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Silver no_smiles Other

DepF

Characterization of

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
unguidepside A (2)
PubChem ↗ CC=C(C)C1=CC(=C(C(=C1C(=O)O)O)C)OC(=O)C2=C(C=C(C=C2C)O)O
DepF
ΔMass: no_smiles Missing dual SMILES or RDKit not validated

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt Other; Other; DepF decarboxylates 2 to 2a. In vitro purified enzyme assay confirmed.

Reaction & quality gates

Mechanism
Other
Evidence type
In vitro
Confidence
High
Data tier
Silver
mass=no_smiles; incomplete_SMILES
Substrate class
Other
Product class
Other

Literature & public identifiers

PubMed
PMID:37719379 ↗
DOI
10.1016/j.apsb.2023.05.036 ↗
UniProt
GenBank
NCBI TaxID

Characterization of the depsidone gene cluster reveals etherification, decarboxylation and multiple halogenations as tailoring steps in depsidone assembly.