OMT

Reinventing metabolic

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping

Substrate

TRIBOA-Glc

PubChem ↗ C1=CC2=C(C=C1O)O[C@@H](C(=O)N2O)O[C@H]3[C@@H]([C@H]([C@@H]([C@H…

OMT

ΔMass: +14.0157 Da mismatch

Product

DIMBOA-Glc

PubChem ↗ COC1=CC2=C(C=C1)N(C(=O)[C@H](O2)O[C@H]3[C@@H]([C@H]([C@@H]([C@H…

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt Other; Other; AsBX7 from Aphelandra squarrosa methylates TRIBOA-Glc to DIMBOA-Glc, demonstrated in vitro and in N. benthamiana.

Reaction & quality gates

Mechanism: Other
Evidence type: In vitro
Confidence: High
Data tier: Quarantine
non-CYP auxiliary enzyme (pathway partner, not cytochrome P450)
Substrate class: Glycosides
Product class: Glycosides

Literature & public identifiers

PubMed: PMID:37812727 ↗
DOI: 10.1073/pnas.2307981120 ↗
UniProt: P46484 ↗
GenBank: —
NCBI TaxID: —

Reinventing metabolic pathways: Independent evolution of benzoxazinoids in flowering plants.