Redox1

Tabernanthe iboga

Apocynaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping

Substrate

dehydroprekuammicine

PubChem ↗ Crowdsource substrate structure

Redox1

ΔMass: no_smiles Missing dual SMILES or RDKit not validated

Product

16(R/S)-deshydroxymethyl stemmadenine

PubChem ↗ Crowdsource product structure

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ion; ion; TiRedox1 coupled with TiGO; products observed at m/z 325.1910 consistent with reduced iminium intermediate.

Reaction & quality gates

Mechanism: Reduction
Evidence type: In vitro
Confidence: High
Data tier: Silver
mass=no_smiles; incomplete_SMILES
Substrate class: Other
Product class: Other

Literature & public identifiers

PubMed: PMID:41478566 ↗
DOI: 10.1016/j.jbc.2025.111120 ↗
UniProt: PX547880 ↗
GenBank: PX547880 ↗
NCBI TaxID: 141617 ↗

Conserved early steps of stemmadenine biosynthesis.