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Quarantine mismatch Cyclization

TPS1

Mosla chinensis

Lamiaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
geranyl diphosphate
PubChem ↗ CC(=CCC/C(=C/COP(=O)(O)OP(=O)(O)O)/C)C
TPS1
ΔMass: -177.9432 Da mismatch
Product
γ-terpinene
PubChem ↗ CC=1CC=C(C(C)C)CC1

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ization; ization; In vitro assay with GPP as substrate; product confirmed by GC-MS.

Reaction & quality gates

Mechanism
Cyclization
Evidence type
In vitro
Confidence
High
Data tier
Quarantine
non-CYP auxiliary enzyme (pathway partner, not cytochrome P450)
Substrate class
Other
Product class
Terpenoids

Literature & public identifiers

PubMed
PMID:41631144 ↗
DOI
10.1093/hr/uhaf263 ↗
UniProt
A0A0M3Q1Q3 ↗
GenBank
NCBI TaxID
516065 ↗

Integrative chromosome-level genomics and metabolomics uncover regulatory networks linking monoterpenoid biosynthesis and glandular trichome formation in <i>Mosla chinensis</i>.