← Back to reactions
Quarantine mismatch Cyclization

TPS5

Mosla chinensis

Lamiaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
geranyl diphosphate
PubChem ↗ CC(=CCC/C(=C/COP(=O)(O)OP(=O)(O)O)/C)C
TPS5
ΔMass: -177.9432 Da mismatch
Product
α-pinene
PubChem ↗ CC1=C[C@H]2C[C@@H](C1)C2(C)C

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ization; ization; In vitro assay with GPP as substrate; product confirmed by GC-MS.

Reaction & quality gates

Mechanism
Cyclization
Evidence type
In vitro
Confidence
High
Data tier
Quarantine
non-CYP auxiliary enzyme (pathway partner, not cytochrome P450)
Substrate class
Other
Product class
Terpenoids

Literature & public identifiers

PubMed
PMID:41631144 ↗
DOI
10.1093/hr/uhaf263 ↗
UniProt
R4JQS2 ↗
GenBank
NCBI TaxID
516065 ↗

Integrative chromosome-level genomics and metabolomics uncover regulatory networks linking monoterpenoid biosynthesis and glandular trichome formation in <i>Mosla chinensis</i>.