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Quarantine mismatch Hydroxylation

OBH

Unknown CYP98A

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
syringalide A 3'-α-L-rhamnopyranoside
PubChem ↗ C[C@H]1[C@@H]([C@H]([C@H]([C@@H](O1)O[C@@H]2[C@H]([C@@H](O[C@@H…
OBH
ΔMass: +0.0000 Da mismatch
Product
verbascoside
PubChem ↗ C[C@H]1[C@@H]([C@H]([C@H]([C@@H](O1)O[C@@H]2[C@H]([C@@H](O[C@@H…

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ation; ation; PbCYP98A192 also converts syringalide A 3'-α-L-rhamnopyranoside to verbascoside.

Reaction & quality gates

Mechanism
Hydroxylation
Evidence type
In vitro
Confidence
High
Data tier
Quarantine
non-CYP auxiliary enzyme (pathway partner, not cytochrome P450)
Substrate class
Other
Product class
Other

Literature & public identifiers

PubMed
PMID:36935606 ↗
DOI
10.1016/j.xplc.2023.100592 ↗
UniProt
—
GenBank
—
NCBI TaxID
—

Complete biosynthesis of the phenylethanoid glycoside verbascoside.

Other reactions by this enzyme

syringalide A 3'-α-L-rhamnopyranoside → verbascoside
Quarantine Hydroxylation mismatch
syringalide A 3'-α-L-rhamnopyranoside → verbascoside
Quarantine Hydroxylation mismatch
syringalide A 3'-α-L-rhamnopyranoside → verbascoside
Quarantine Hydroxylation mismatch
syringalide A 3'-α-L-rhamnopyranoside → verbascoside
Quarantine Hydroxylation mismatch
ligupurpuroside B → ligurobustoside N
Quarantine Hydroxylation ΔMass ✓
ligupurpuroside B → ligurobustoside N
Quarantine Hydroxylation ΔMass ✓