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Silver no_smiles Hydroxylation

NdsC

Evidence from

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
NdsC
ΔMass: no_smiles Missing dual SMILES or RDKit not validated
Product
hydroxy-CJ20,557
PubChem ↗ Crowdsource product structure

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ation; ation; NdsC is a cytochrome P450 oxygenase; hydroxylation of the 3-methyl group of 3-MOA unit in CJ-20,557 (compound 1) to produce hydroxy-CJ20,557 (compound 10). Evidence from heterologous expression of ndsABC in A. nidulans.

Reaction & quality gates

Mechanism
Hydroxylation
Evidence type
In vivo
Confidence
High
Data tier
Silver
mass=no_smiles; incomplete_SMILES
Substrate class
Other
Product class
Other

Literature & public identifiers

PubMed
PMID:41122484 ↗
DOI
10.1039/d5sc05442g ↗
UniProt
GenBank
NCBI TaxID

Heterologous expression of an <i>in planta</i>-upregulated gene cluster in the wheat pathogen <i>Parastagonospora nodorum</i> establishes the biosynthesis of methylene-bridged depsides.