Quarantine
no_smiles
Oxidation
Substrate reaction site
Product reaction site
MCS substructure diff highlighting · RDKit atom mapping
Substrate
paspalinine (9)
PubChem ↗
C[C@]12CC[C@]34C(=CC(=O)[C@H](O3)C(O4)(C)C)[C@@]1(CC[C@@H]5[C@@…
LtmJ
ΔMass: no_smiles
Missing dual SMILES or RDKit not validated
Evidence trail
Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.
Source text excerpt ation; ation; Product 10 is putative; structure not fully characterized.
Reaction & quality gates
- Mechanism
- Oxidation
- Evidence type
- In vivo
- Confidence
- Medium
- Data tier
- Quarantine
non-CYP auxiliary enzyme (pathway partner, not cytochrome P450) - Substrate class
- Other
- Product class
- Other
Literature & public identifiers
- PubMed
- PMID:32677206 ↗
- DOI
- 10.1002/anie.202007280 ↗
- UniProt
- —
- GenBank
- —
- NCBI TaxID
- —
Biosynthesis of Indole Diterpene Lolitrems: Radical-Induced Cyclization of an Epoxyalcohol Affording a Characteristic Lolitremane Skeleton.