← Back to reactions
Silver no_smiles Hydroxylation

CYP71D375

Salvia miltiorrhiza CYP71D

Lamiaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
4-methylenemiltirone
PubChem ↗ CC(C)C1=CC2=C(C3=C(C=C2)C(=C)CCC3)C(=O)C1=O
CYP71D375
ΔMass: no_smiles Missing dual SMILES or RDKit not validated
Product
16-hydroxy-4-methylenemiltirone
PubChem ↗ Crowdsource product structure

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ation; ation; CYP71D375 accepts 4-methylenemiltirone (6) as substrate; product 10 inferred as 16-hydroxy-4-methylenemiltirone based on MS, retention time, and chemical logic.

Reaction & quality gates

Mechanism
Hydroxylation
Evidence type
In vitro
Confidence
Medium
Data tier
Silver
mass=no_smiles; incomplete_SMILES
Substrate class
Other
Product class
Other

Literature & public identifiers

PubMed
PMID:33514704 ↗
DOI
10.1038/s41467-021-20959-1 ↗
UniProt
A0A5A4JQD7 ↗
GenBank
NCBI TaxID
226208 ↗

Expansion within the CYP71D subfamily drives the heterocyclization of tanshinones synthesis in Salvia miltiorrhiza.